Ian Wark Research Institute, University of South Australia, Mawson Lakes Campus, Adelaide SA 5095, Australia.
J Colloid Interface Sci. 2010 Aug 15;348(2):460-8. doi: 10.1016/j.jcis.2010.04.073. Epub 2010 May 26.
The foamability of a triblock copolymer solution was strongly influenced by the presence of particles. The stability of the foam was evaluated by measuring the foam volume, the drainage of water and particles, and the bubble size as a function of time. The higher stability of foams produced with hydrophilic quartz particles, compared with hydrophobic graphite particles, was related to the presence of quartz aggregates in the lamellae and Plateau borders reducing water drainage, and therefore thin film rupture and bubble coalescence. The copolymer adsorbed slightly more on the hydrophobic graphite, causing the particles to disperse and drain, with the water out of the foam, whereas the hydrophilic quartz aggregated and remain in the lamellar and Plateau borders of the foam.
胶束共聚物溶液的起泡能力受到颗粒存在的强烈影响。通过测量泡沫体积、水和颗粒的排水以及泡沫中气泡大小随时间的变化,评估了泡沫的稳定性。与疏水性石墨颗粒相比,亲水性石英颗粒产生的泡沫具有更高的稳定性,这与在薄片和Plateau 边界中存在石英聚集体有关,这减少了水的排出,从而减少了薄膜破裂和气泡聚并。共聚物在疏水性石墨上稍微吸附更多,导致颗粒分散和排水,泡沫中的水排出,而亲水性石英则聚集并留在泡沫的薄片和 Plateau 边界中。