State Key Laboratory of Supramolecular Structure and Materials, Jilin University, 2699 Qianjin Avenue, Changchun 130012, PR China.
Spectrochim Acta A Mol Biomol Spectrosc. 2010 Sep 15;77(1):226-31. doi: 10.1016/j.saa.2010.05.013. Epub 2010 May 24.
The salen-type Schiff base (2,2'-bis(2-hydroxybenzylideneamino)-1,1'-binaphthyl (BHB)) has been synthesized and characterized. Exhibiting absorption and fluorescence changes in the presence of Zn(2+) in chloroform and ethanol mixed solution, BHB could be used as a fluorescent chemosensor for the detection of Zn(2+). Furthermore, by monitoring the fluorescence and absorbance as output signals, BHB can function as a combinatorial logic circuit for a molecular half-subtractor with Zn(2+) and UV irradiation as input variables.
席夫碱(2,2'-双(2-羟基苯亚甲基)-1,1'-联萘(BHB))已被合成并进行了表征。在氯仿和乙醇混合溶液中存在 Zn(2+)时,BHB 表现出吸收和荧光变化,因此可作为荧光化学传感器用于检测 Zn(2+)。此外,通过监测荧光和吸光度作为输出信号,BHB 可以作为具有 Zn(2+)和紫外光辐照作为输入变量的分子半减器的组合逻辑电路。