侧向嫁接杆中的自组织螺旋柱。

Self-organized spiral columns in laterally grafted rods.

机构信息

Center for Supramolecular Nano-Assembly and Department of Chemistry, Seoul National University, Gwanak-ro 599, Seoul 151-747, Korea.

出版信息

Chem Commun (Camb). 2010 Jul 21;46(27):4896-8. doi: 10.1039/c0cc00132e. Epub 2010 Jun 11.

DOI:10.1039/c0cc00132e

PMID:20539894

Abstract

Attachment of a flexible coil on the mid-part of a rigid rod block generates T-shaped rod-coil block molecules that self-assemble into a stepped column. These layers, in turn, self-curve into a spiral column with tunable core structure in the solid state.

摘要

在刚性杆块的中部附上一个柔性线圈会产生 T 形杆-线圈块分子，这些分子会自组装成阶状柱体。这些层继而在固态中自卷曲成具有可调核结构的螺旋柱体。