铜和金金属有机骨架在均相和多相催化剂之间架起桥梁，用于烯烃环丙烷化反应。
Cu and Au metal-organic frameworks bridge the gap between homogeneous and heterogeneous catalysts for alkene cyclopropanation reactions.
机构信息
Inst. Tecnología Química, UPV-CSIC, Universidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas, Avda los Naranjos, s/n, 46022 Valencia, Spain.
出版信息
Chemistry. 2010 Aug 23;16(32):9789-95. doi: 10.1002/chem.201000278.
The copper and gold metal-organic frameworks (MOFs) Cu(3)(BTC)(2)(H(2)O)(3), [Cu(3)(BTC)(2)] (BTC=benzene-1,3,5-tricarboxylate), and IRMOF-3-SI-Au are active and reusable solid catalysts for the cyclopropanation of alkenes with high chemo- and diastereoselectivities. This type of material gives better results than previous solid catalysts while working together with the homogeneous catalysts. These MOFs can help to bridge the gap between homogeneous and heterogeneous catalysis.
铜和金金属有机骨架（MOFs）Cu(3)(BTC)(2)(H(2)O)(3)、[Cu(3)(BTC)(2)]（BTC=苯-1,3,5-三甲酸）和 IRMOF-3-SI-Au 是用于烯烃环丙烷化反应的高效、可重复使用的固体催化剂，具有高的化学选择性和非对映选择性。这种材料与均相催化剂一起使用时，比以前的固体催化剂效果更好。这些 MOFs 可以帮助弥合均相和多相催化之间的差距。
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