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[近红外光谱法与化学计量学用于橄榄油品质分析及掺假定量检测]

[Quality analysis of olive oil and quantification detection of adulteration in olive oil by near-infrared spectrometry and chemometrics].

作者信息

Zhuang Xiao-Li, Xiang Yu-Hong, Qiang Hong, Zhang Zhuo-Yong, Zou Ming-Qiang, Zhang Xiao-Fang

机构信息

Department of Chemistry, Capital Normal University, Beijing 100048, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2010 Apr;30(4):933-6.

Abstract

Discriminant analysis was used to classify 20 olive oil samples based on their near-infrared (NIR) spectra. The samples were successfully classified into two categories which are consistent with extra virgin olive oil and ordinary olive oil defined in the products. The NIR spectra of olive-oil mixtures containing colza oil, corn oil, peanut oil, camellia oil, sunflower oil, and poppy seed oil were collected, respectively. The volume percent of adulterants ranged from 0 to 100%. The best spectrum bands for analysis were selected before developing partial least-squares (PLS) calibration models. The relative errors of prediction ranged from -5.67% to 5.61%. Results showed that the method combined with chemometrics methods and near-infrared spectrometry is simple, fast and credible for qualitative and quantitative analyses of olive oil samples.

摘要

判别分析用于根据近红外(NIR)光谱对20个橄榄油样品进行分类。这些样品被成功分为两类,这与产品中定义的特级初榨橄榄油和普通橄榄油一致。分别收集了含有菜籽油、玉米油、花生油、山茶油、向日葵油和罂粟籽油的橄榄油混合物的近红外光谱。掺假物的体积百分比范围为0至100%。在建立偏最小二乘(PLS)校准模型之前,选择了最佳分析光谱带。预测相对误差范围为-5.67%至5.61%。结果表明,该方法结合化学计量学方法和近红外光谱法,对橄榄油样品进行定性和定量分析简单、快速且可靠。

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