八员环二阴离子的包合物在一种不寻常的有机/无机镧系元素三明治型夹心配合物中。
Encapsulation of cyclooctatetraenyl dianion in an unusual organic/inorganic lanthanide triple-decker sandwich complex.
机构信息
Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Universitätsplatz 2, 39106, Magdeburg, Germany.
出版信息
Dalton Trans. 2010 Aug 7;39(29):6629-31. doi: 10.1039/c0dt00094a. Epub 2010 Jun 14.
PMID:20548992
Abstract
Treatment of (COT)Nd(THF)(2)(mu-Cl) with dilithium tetraphenyldisiloxanediolate, (LiOSiPh(2))(2)O, in a molar ratio of 1 : 4 afforded the novel organic/inorganic triple-decker complex (mu-eta(8):eta(8)-COT)Nd{(Ph(2)SiO)(2)O}(2){Li(THF)(2)}{Li(THF)} (1) which was structurally characterized by X-ray diffraction.
摘要
(COT)Nd(THF)(2)(mu-Cl)与二锂四苯基亚硅氧烷二聚醇（LiOSiPh(2))(2)O 以摩尔比 1:4 反应，得到新型有机/无机三明治配合物(mu-eta(8):eta(8)-COT)Nd{(Ph(2)SiO)(2)O}(2){Li(THF)(2)}{Li(THF)}（1），通过 X 射线衍射对其结构进行了表征。
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