有机镧系卤化物合成子——单官能化镧系(II)化合物的新一般路线？
Organolanthanoid-halide synthons--a new general route to monofunctionalized lanthanoid(II) compounds?
机构信息
School of Chemistry, Monash University, Clayton, Victoria 3800, Australia.
出版信息
Chem Commun (Camb). 2010 Jul 28;46(28):5076-8. doi: 10.1039/c0cc01317j. Epub 2010 Jun 16.
PMID:20552131
Abstract
New Eu(II) and Yb(II) complexes [Ln(Ph(2)pz)I(thf)(4)] were synthesized from the corresponding metals and 3,5-diphenylpyrazole (HPh(2)pz) using iodobenzene as oxidizing agent. In the absence of the pyrazole, the charge separated Yb(II)/Yb(III) complex [{Yb(dme)(4)}{YbPh(4)(dme)}(2)] has been isolated.
摘要
新的 Eu(II) 和 Yb(II) 配合物 [Ln(Ph(2)pz)I(thf)(4)] 是由相应的金属和 3,5-二苯基吡唑 (HPh(2)pz) 与碘苯作为氧化剂反应合成的。在没有吡唑的情况下，已经分离出电荷分离的 Yb(II)/Yb(III) 配合物 [{Yb(dme)(4)}{YbPh(4)(dme)}(2)]。
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