Marciniak Andrzej
Department of Physical Chemistry, Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland; E-Mail:
Int J Mol Sci. 2010 Apr 27;11(5):1973-90. doi: 10.3390/ijms11051973.
The Hildebrand's solubility parameters have been calculated for 18 ionic liquids from the inverse gas chromatography measurements of the activity coefficients at infinite dilution. Retention data were used for the calculation. The solubility parameters are helpful for the prediction of the solubility in the binary solvent mixtures. From the solubility parameters, the standard enthalpies of vaporization of ionic liquids were estimated.
通过无限稀释下活度系数的反相气相色谱测量,计算了18种离子液体的希尔德布兰德溶解度参数。保留数据用于计算。溶解度参数有助于预测在二元溶剂混合物中的溶解度。根据溶解度参数,估算了离子液体的标准汽化焓。