Polymer Materials and Interfaces Laboratory and Department of Chemical Engineering Virginia Polytechnic Institute and State University Blacksburg, VA.
Biotechnol Prog. 1985 Mar;1(1):33-8. doi: 10.1002/btpr.5420010108.
Soy flour is processed in single screw extruders to yield textured vegetable protein used as meat extenders and replacements. The fundamental processes which take place in extrusion cooking of soy doughs are poorly understood from an engineering point of view. This paper is concerned with gaining an understanding of extrusion cooking in order to develop a quantitative model of this process in single screw extruders. Rheological and thermodynamic data are obtained over a range of conditions found in the extrusion process and this data is used both in understanding and modeling the extrusion cooking process.In particular, differential scanning calorimetry (DSC) has been used to determine changes in the enthalpy of soy doughs at various moisture levels. It is observed that in general the enthalpy changes are small (e.g. of the order of 1.0 cal/g) and endothermic. However, if the dough is subjected to shear and thermal history, then the enthalpy changes become significant. The viscosity of the dough exhibits a mild increase in the temperature range where the endotherms are observed in the DSC data. Based on the results of this study, it is concluded that cooking does not involve cross-linking of the proteins but more likely a conformation change of the molecules. Also, it is found that for the 40% to 60% added moisture soy flour dough systems, the rheological properties can be modeled using a Bingham model modified with a shear rate dependent viscosity.
大豆粉在单螺杆挤出机中加工,制成用于肉类增稠和替代物的组织化植物蛋白。从工程角度来看,挤压蒸煮过程中发生的基本过程还没有得到很好的理解。本文旨在深入了解挤压蒸煮过程,以便在单螺杆挤出机中开发该过程的定量模型。在挤压过程中发现的一系列条件下,获得了流变学和热力学数据,并将该数据用于理解和模拟挤压蒸煮过程。特别是,差示扫描量热法(DSC)已用于确定在不同水分水平下大豆面团的焓变。观察到一般焓变很小(例如约 1.0 卡/克),并且是吸热的。但是,如果面团受到剪切和热历史的影响,那么焓变就会变得显著。面团的粘度在 DSC 数据中观察到的吸热温度范围内略有增加。基于这项研究的结果,可以得出结论,蒸煮不涉及蛋白质的交联,而更可能是分子构象的变化。此外,还发现对于添加水分 40%至 60%的大豆粉面团系统,流变性能可以使用带有剪切速率相关粘度的宾汉模型进行建模。