均相金催化超越假设与设想——特性中间体。
Homogeneous gold catalysis beyond assumptions and proposals--characterized intermediates.
机构信息
Organisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
出版信息
Angew Chem Int Ed Engl. 2010 Jul 19;49(31):5232-41. doi: 10.1002/anie.200907078.
PMID:20572216
Abstract
Gold catalysis is a very active area in the field of catalysis research. New reactions are published every week, amazing changes in the connectivity are often observed, the number of applications in total synthesis is increasing...--but what are the mechanisms of these reactions? Sound information can be provided by knowledge about the intermediates of these reactions.
摘要
金催化是催化研究领域非常活跃的一个分支。每周都有新的反应被发表，连接性方面的惊人变化经常被观察到，在全合成中的应用数量也在增加……但是这些反应的机制是什么呢？通过对这些反应中间体的了解，可以提供有价值的信息。
Zotero 插件