超声处理对用于复合焊料的硅纳米颗粒镀金的影响。
The effect of ultrasound on the gold plating of silica nanoparticles for use in composite solders.
机构信息
The Sonochemistry Centre, Coventry University, Faculty of Health and Life Science, Priory Street, Coventry, CV1 5FB, UK.
出版信息
Ultrason Sonochem. 2011 Jan;18(1):37-41. doi: 10.1016/j.ultsonch.2010.04.010. Epub 2010 May 12.
In order to produce electronic devices that can survive harsh environments it is essential that the solder joints are very reliable and this has led to the development of composite solders. One approach to the manufacture of such solders is to disperse silica nanoparticles into it to improve their mechanical and fatigue characteristics. However, this is difficult to achieve using bare silica particles because they are not "wettable" in the solder matrix and so cannot be dispersed efficiently. In an attempt to alleviate this issue it has been found that if the silica nanoparticles are first plated with gold then this problem of wetting can, to some extent, be overcome. However, the particles must be completely encapsulated with gold which, using the method previously described by workers at Kings College London, was found to be difficult to accomplish. In this short communication the effect of ultrasound on the gold coverage is described. Different frequencies of ultrasound were used (20, 850 and 1176 kHz) and it was found that higher frequencies of ultrasound improved the coverage and dispersion of the gold nanoparticles over silica during the seeding step compared to simple mechanical agitation. This subsequently led to a more complete encapsulation of gold in the plating stage.
为了生产能够在恶劣环境中生存的电子设备,焊点必须非常可靠,这导致了复合焊料的发展。制造这种焊料的一种方法是将纳米二氧化硅分散到其中,以提高其机械和疲劳特性。然而,使用裸二氧化硅颗粒很难实现这一点,因为它们在焊料基体中“不可润湿”,因此不能有效地分散。为了缓解这个问题,人们发现,如果先将纳米二氧化硅颗粒镀上金,那么在一定程度上可以克服润湿问题。然而,颗粒必须完全被金包裹,而使用伦敦国王学院的工作人员之前描述的方法,发现很难实现这一点。在本简短通讯中,描述了超声对金覆盖层的影响。使用了不同频率的超声(20、850 和 1176 kHz),结果发现与简单的机械搅拌相比,超声的更高频率在播种步骤中提高了金纳米颗粒在二氧化硅上的覆盖和分散程度,从而导致在镀覆阶段更完全地包裹金。