金属离子驱动的光收集天线的形成通过敏化发光和荧光各向异性研究。
Metal ion driven formation of a light-harvesting antenna investigated by sensitized luminescence and fluorescence anisotropy.
机构信息
Dipartimento di Chimica G. Ciamician, Università di Bologna, via Selmi 2, I-40126 Bologna, Italy.
出版信息
Chem Commun (Camb). 2010 May 28;46(20):3571-3. doi: 10.1039/c001235a. Epub 2010 Mar 23.
DOI:10.1039/c001235a
PMID:20582357
Abstract
Zn(ii) complexation drives the formation of a light-harvesting antenna constituted by two multicomponent luminescent ligands: a cyclam-cored dendrimer decorated at the periphery with 16 naphthyl units and an anthracene-based molecular clip.
摘要
Zn(ii) 配合物驱动由两个多组分发光配体组成的光收集天线的形成：一个以环戊二烯为核的树枝状大分子，在其外围用 16 个萘基单元和一个基于蒽的分子夹进行修饰。
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