镍(II)和铜(II)不对称 N2O2 希夫碱配合物的合成、光谱、电化学和热研究。
Synthesis, spectroscopy, electrochemistry and thermal study of Ni(II) and Cu(II) unsymmetrical N2O2 Schiff base complexes.
机构信息
Chemistry Department, Yasouj University, Yasouj, Iran.
出版信息
Spectrochim Acta A Mol Biomol Spectrosc. 2010 Oct 1;77(2):424-9. doi: 10.1016/j.saa.2010.06.008. Epub 2010 Jun 11.
The new tetradentate unsymmetrical N(2)O(2) Schiff base ligands, Ni(II) and Cu(II) complexes were synthesised and chracterized by IR, UV-vis, (1)H NMR and elemental analysis. The electrochemical properties of the Ni(II) complexes were investigated. The thermogravimetry of the Ni(II) and Cu(II) complexes were carried out in the range of 20-700 degrees C. Decomposition of synthesised complexes is related to the Schiff base characteristics.
新的四齿非对称 N(2)O(2)希夫碱配体、Ni(II)和 Cu(II)配合物被合成并通过红外光谱、紫外可见光谱、（1）H NMR 和元素分析进行了表征。Ni(II)配合物的电化学性质进行了研究。Ni(II)和 Cu(II)配合物的热重分析在 20-700 摄氏度范围内进行。合成配合物的分解与希夫碱的特性有关。
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