合成、分子建模及光谱表征新型 16 元混合供体大环席夫碱配体的镍(II)、铜(II)配合物，该配体包含一个悬垂醇官能团。
Synthesis, molecular modeling and spectroscopic characterization of nickel(II), copper(II), complexes of new 16-membered mixed-donor macrocyclic schiff base ligand incorporating a pendant alcohol function.
机构信息
Department of Chemistry, Zakir Husain College (University of Delhi), J.L. Nehru Marg, New Delhi 110002, India.
出版信息
Spectrochim Acta A Mol Biomol Spectrosc. 2011 Sep;79(5):1326-30. doi: 10.1016/j.saa.2011.04.063. Epub 2011 Jun 1.
Complexes of Cu(II) and Ni(II) of the composition [M(L)X] [where M=Ni(II), Cu(II) and X=Cl-, NO3-, CH3COO-] were synthesized with 1,5-dioxo-9,10-diaza-3,ol-tribenzo-(7,6,10,11,14,15) peptadecane, a N2O2 macrocyclic ligand. The complexes were characterized by elemental analysis, molar conductance measurements, UV-vis, IR, 1H NMR, 13C NMR, EPR and molecular modeling studies. All the complexes are non-electrolyte in nature. On the basis of spectral studies, an octahedral geometry has been assigned for Ni(II) complexes and a tetragonal geometry for Cu(II) complexes.
用 1,5-二氧代-9,10-二氮杂-3,8,11,12,14,15-六苯并-（7,6,10,11,14,15）十七烷，一种 N2O2 大环配体，合成了组成 [M(L)X] 的 [Cu(II)] 和 [Ni(II)] 配合物[其中 M=Ni(II)，Cu(II) 和 X=Cl-，NO3-，CH3COO-]。通过元素分析、摩尔电导率测量、UV-vis、IR、1H NMR、13C NMR、EPR 和分子建模研究对配合物进行了表征。所有配合物均为非电解质。根据光谱研究，Ni(II) 配合物的几何构型为八面体，Cu(II) 配合物的几何构型为四方锥。
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