Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, Canada.
Chem Soc Rev. 2010 Oct;39(10):3612-20. doi: 10.1039/b926226c. Epub 2010 Jul 8.
This tutorial review describes metal-based anion receptors in the context of first- and second-sphere coordination. Selected examples (case studies) are used to show how metal ions can be used to (1) organise hydrogen-bond donor sites on ligands in order to bind anions, (2) influence the conformation of ligands to enhance anion binding, (3) alter the binding conformation of a receptor depending on the solvent and (4) develop a receptor to target a specific anion (sulfate) for sequestration.
本教程综述描述了第一和第二配体场中基于金属的阴离子受体。选用的实例（案例研究）用于说明金属离子如何用于：(1) 组织配体上氢键供体位点以结合阴离子；(2) 影响配体的构象以增强阴离子结合；(3) 根据溶剂改变受体的结合构象；(4) 开发受体以靶向特定阴离子（硫酸盐）进行螯合。
