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Org Lett. 2010 Aug 6;12(15):3372-5. doi: 10.1021/ol101180r.
A series of ferrocene-based electroactive molecules (EAMs) containing maleimide and disulfide groups in different asymmetric and branched architectures were designed and synthesized. Stable monolayers of each EAM on gold electrodes were confirmed by cyclic voltammetry. Importantly, these EAMs expand the repertoire of monolayer building blocks amenable to modular biofunctionalization for applications in electrochemical biosensor fabrication.
设计并合成了一系列具有不同不对称和支化结构的含马来酰亚胺和二硫键的二茂铁基电活性分子（EAMs）。通过循环伏安法证实了每种 EAM 在金电极上的稳定单层。重要的是，这些 EAMs 扩展了可用于电化学生物传感器制造的模块化生物功能化的单层构建块的范围。
