Lawrence Livermore National Laboratory, Livermore, California 94551, USA.
Astrobiology. 2010 Jun;10(5):561-8. doi: 10.1089/ast.2009.0427.
A mechanism for creating amino acid enantiomerism that always selects the same large-scale chirality is identified, and subsequent chemical replication and galactic mixing that would populate the Galaxy with the predominant species is described. This involves (1) the spin of the 14N in the amino acids, or in precursor molecules from which amino acids might be formed, that couples to the chirality of the molecules; (2) the neutrinos emitted from the supernova, together with the magnetic field from the nascent neutron star or black hole formed from the supernova, which selectively destroy one orientation of the 14N and thus select the chirality associated with the other 14N orientation; (3) chemical evolution, by which the molecules replicate and evolve to more complex forms of a single chirality on a relatively short timescale; and (4) galactic mixing on a longer timescale that mixes the selected molecules throughout the Galaxy.
确定了一种产生氨基酸对映异构体的机制,该机制始终选择相同的大规模手性,并且描述了随后的化学复制和星系混合,这将使主要物种充满星系。这涉及到:(1)氨基酸中 14N 的旋转,或者可能形成氨基酸的前体分子中的旋转,与分子的手性耦合;(2)来自超新星的中微子,以及来自超新星形成的新生中子星或黑洞的磁场,它们选择性地破坏 14N 的一个取向,从而选择与另一个 14N 取向相关的手性;(3)化学进化,通过这种进化,分子在相对较短的时间尺度上复制并演变成单一手性的更复杂形式;(4)在更长的时间尺度上的星系混合,将选定的分子混合在整个星系中。