Boyd Richard N, Kajino Toshitaka, Onaka Takashi
Lawrence Livermore National Laboratory, Livermore, CA 94550, USA.
Int J Mol Sci. 2011;12(6):3432-44. doi: 10.3390/ijms12063432. Epub 2011 May 31.
A mechanism for creating an enantioenrichment in the amino acids, the building blocks of the proteins, that involves global selection of one handedness by interactions between the amino acids and neutrinos from core-collapse supernovae is defined. The chiral selection involves the dependence of the interaction cross sections on the orientations of the spins of the neutrinos and the (14)N nuclei in the amino acids, or in precursor molecules, which in turn couple to the molecular chirality. It also requires an asymmetric distribution of neutrinos emitted from the supernova. The subsequent chemical evolution and galactic mixing would ultimately populate the Galaxy with the selected species. The resulting amino acids could either be the source thereof on Earth, or could have triggered the chirality that was ultimately achieved for Earth's proteinaceous amino acids.
定义了一种在构成蛋白质的氨基酸中产生对映体富集的机制,该机制涉及通过氨基酸与核心坍缩超新星产生的中微子之间的相互作用对一种手性进行全局选择。手性选择涉及相互作用截面取决于中微子和氨基酸或前体分子中(14)N原子核自旋的取向,而这又与分子手性相关联。它还需要超新星发射的中微子的不对称分布。随后的化学演化和星系混合最终会使银河系中充满被选择的物种。由此产生的氨基酸要么是地球上氨基酸的来源,要么可能引发了最终在地球蛋白质氨基酸中实现的手性。