基于全氟环戊烯的二芳基乙烯，带有两个三吡啶基部分 - 合成，光化学性质和过渡金属离子的影响。
A perfluorocyclopentene based diarylethene bearing two terpyridine moieties - synthesis, photochemical properties and influence of transition metal ions.
机构信息
Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, D-12489 Berlin, Germany.
出版信息
Beilstein J Org Chem. 2010 May 26;6:53. doi: 10.3762/bjoc.6.53.
The synthesis of a perfluorocyclopentene based diarylethene bearing two terpyridine units is reported. Furthermore studies of the free ligand's photochromism and investigations regarding the influence of various transition metal ions on the photochromic reaction are presented. The photochromism of the central diarylethene unit is strongly dependent on the transition metal present, vice versa the photochromic reaction seems to influence the MLCT transition of a binuclear Ru(II) complex.
报告了一种基于全氟环戊烯的二芳基乙烯的合成，该二芳基乙烯带有两个三吡啶基单元。此外，还研究了游离配体的光致变色，并研究了各种过渡金属离子对光致变色反应的影响。中心二芳基乙烯单元的光致变色强烈依赖于存在的过渡金属，反之，光致变色反应似乎会影响双核 Ru(II)配合物的 MLCT 跃迁。
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