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本文引用的文献

1
Synthesis and crystal and molecular structure of a tetranuclear cluster based on the rhenium(III)-bisorganohydrazino core: [Re(HNNC(4)H(3)N(2))(NNC(4)H(3)N(2))(OCH(3))(2)](4).基于铼（III）-双有机肼基核的四核簇合物的合成、晶体结构和分子结构：[Re(HNNC(4)H(3)N(2))(NNC(4)H(3)N(2))(OCH(3))(2)](4)
Inorganica Chim Acta. 2000 Sep 1;307(1-2):160-163. doi: 10.1016/S0020-1693(00)00207-3.
2
Oxorhenium(V) complexes containing tridentate Schiff-base and monothiol coligands.含有三齿席夫碱和单硫醇共配体的铼（V）氧配合物。
Inorganica Chim Acta. 2000 Apr 20;300-302:517-524. doi: 10.1016/S0020-1693(99)00586-1.
3
99mTc-Labeled Small Peptides as Diagnostic Radiopharmaceuticals.99m锝标记的小肽作为诊断性放射性药物
Chem Rev. 1999 Sep 8;99(9):2235-68. doi: 10.1021/cr980436l.
4
Technetium Complexes of a Hydrazinonicotinamide-Conjugated Cyclic Peptide and 2-Hydrazinopyridine: Synthesis and Characterization.
Inorg Chem. 1999 Mar 22;38(6):1326-1335. doi: 10.1021/ic980973o.
5
Synthesis and Characterization of Organohydrazino Complexes of Technetium, Rhenium, and Molybdenum with the {M(eta(1)-H(x)()NNR)(eta(2)-H(y)()NNR)} Core and Their Relationship to Radiolabeled Organohydrazine-Derivatized Chemotactic Peptides with Diagnostic Applications.锝、铼和钼的具有{M(η(1)-H(x)NNR)(η(2)-H(y)NNR)}核心的有机肼基配合物的合成与表征及其与具有诊断应用的放射性标记有机肼衍生趋化肽的关系。
Inorg Chem. 1998 Jun 1;37(11):2701-2716. doi: 10.1021/ic970352f.
6
Biological evaluation of thrombus imaging agents utilizing water soluble phosphines and tricine as coligands when used to label a hydrazinonicotinamide-modified cyclic glycoprotein IIb/IIIa receptor antagonist with 99mTc.
Bioconjug Chem. 1997 Mar-Apr;8(2):155-60. doi: 10.1021/bc970001p.
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Labeling a hydrazino nicotinamide-modified cyclic IIb/IIIa receptor antagonist with 99mTc using aminocarboxylates as coligands.
Bioconjug Chem. 1996 Jan-Feb;7(1):63-71. doi: 10.1021/bc950069+.
8
Technetium-99m-labeled chemotactic peptides: comparison with indium-111-labeled white blood cells for localizing acute bacterial infection in the rabbit.锝-99m标记的趋化肽：与铟-111标记的白细胞在兔体内定位急性细菌感染的比较。
J Nucl Med. 1993 Dec;34(12):2176-81.
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Technetium-99m-labeled hydrazino nicotinamide derivatized chemotactic peptide analogs for imaging focal sites of bacterial infection.
J Nucl Med. 1993 Nov;34(11):1964-74.
10
Homodimeric and heterodimeric bis(amino thiol) oxometal complexes with rhenium(V) and technetium(V). Control of heterodimeric complex formation and an approach to metal complexes that mimic steroid hormones.含铼（V）和锝（V）的同二聚体和异二聚体双（氨基硫醇）氧金属配合物。异二聚体配合物形成的控制以及一种模拟甾体激素的金属配合物的方法。
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含硫醇盐和席夫碱共配体的铼双肼基嘧啶核配合物的合成与结构表征

Syntheses and structural characterization of rhenium-bis-hydrazinopyrimidine core complexes with thiolate and Schiff base coligands.

作者信息

Femia Frank J, Chen Xiaoyuan, Maresca Kevin P, Babich John W, Zubieta Jon

机构信息

Room 1 -014, Department of Chemistry, Syracuse University, Syracuse, NY 13244 -4100, USA.

出版信息

Inorganica Chim Acta. 2000 Dec 15;310(2):210-216. doi: 10.1016/S0020-1693(00)00287-5.

DOI:10.1016/S0020-1693(00)00287-5
PMID:20640229
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2904462/
Abstract

The reaction of perrhenate with 2-hydrazinopyrimidine in MeOH-HCl yields [ReCl(3)(eta(1)-NNC(4)H(3)N(2)H)(eta(2)-HNNC(4)H(3)N(2))] (1). The analogous reaction with Na(2)MoO(4) yields [MoCl(3)(eta(1)-NNC(4)H(3)N(2)H)(eta(2)-HNNHC(4)H(3)N(2))] (1a). The reaction of 1 with pyrimidine-2-thiol and triethylamine produces [Re(eta(1)-C(4)H(3)N(2)S)(eta(2)-C(4)H(3)N(2)S)(eta(1)-NNC(4)H(3)N(2))(eta(2)-HNNC(4)H(3)N(2))] (2), while reaction of 1 with the Schiff base HSC(6)H(4)N=C(H)C(6)H(4)OH provides [Re(eta(3)-SC(6)H(4)N=C(H)C(6)H(4)O)(eta(1)-NNC(4)H(3)N(2))(eta(2)-C(6)H(4)O)(eta(1)-NNC(5)H(4)N)(eta(2)-HNNC(5)H(4)N)] (4), was also synthesized by reacting [ReCl(3)(eta(1)-NNC(5)H(4)NH)(eta(2)-HNNC(5)H(4)N)] with HSC(6)H(4)N=C(H)C(6)H(4)OH. The crystal structures of 1-4 have been determined.

摘要

高铼酸盐与2-肼基嘧啶在甲醇-盐酸中反应生成[ReCl(3)(η(1)-NNC(4)H(3)N(2)H)(η(2)-HNNC(4)H(3)N(2))]（1）。与钼酸钠的类似反应生成[MoCl(3)(η(1)-NNC(4)H(3)N(2)H)(η(2)-HNNHC(4)H(3)N(2))]（1a）。1与嘧啶-2-硫醇和三乙胺反应生成[Re(η(1)-C(4)H(3)N(2)S)(η(2)-C(4)H(3)N(2)S)(η(1)-NNC(4)H(3)N(2))(η(2)-HNNC(4)H(3)N(2))]（2），而1与席夫碱HSC(6)H(4)N=C(H)C(6)H(4)OH反应生成[Re(η(3)-SC(6)H(4)N=C(H)C(6)H(4)O)(η(1)-NNC(4)H(3)N(2))(η(2)-C(6)H(4)O)(η(1)-NNC(5)H(4)N)(η(2)-HNNC(5)H(4)N)]（4），[ReCl(3)(η(1)-NNC(5)H(4)NH)(η(2)-HNNC(5)H(4)N)]与HSC(6)H(4)N=C(H)C(6)H(4)OH反应也合成了（4）。已测定了1 - 4的晶体结构。