首个基于单核铜（I）配合物的催化酪氨酸酶模型系统：动力学与机制 - Suppr

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The first catalytic tyrosinase model system based on a mononuclear copper(I) complex: kinetics and mechanism.

作者信息

Rolff Malte, Schottenheim Julia, Peters Gerhard, Tuczek Felix

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Strasse 2, 24098 Kiel, Germany.

出版信息

Angew Chem Int Ed Engl. 2010 Aug 23;49(36):6438-42. doi: 10.1002/anie.201000973.

DOI:10.1002/anie.201000973

PMID:20652917

Abstract

摘要

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The first catalytic tyrosinase model system based on a mononuclear copper(I) complex: kinetics and mechanism.

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The first catalytic tyrosinase model system based on a mononuclear copper(I) complex: kinetics and mechanism.

作者信息

Rolff Malte, Schottenheim Julia, Peters Gerhard, Tuczek Felix

机构信息

Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, Max-Eyth-Strasse 2, 24098 Kiel, Germany.

出版信息

Angew Chem Int Ed Engl. 2010 Aug 23;49(36):6438-42. doi: 10.1002/anie.201000973.

DOI:10.1002/anie.201000973

PMID:20652917

Abstract

摘要

相似文献

The first catalytic tyrosinase model system based on a mononuclear copper(I) complex: kinetics and mechanism.

Angew Chem Int Ed Engl. 2010 Aug 23;49(36):6438-42. doi: 10.1002/anie.201000973.

Kinetic evaluation of phenolase activity of tyrosinase using simplified catalytic reaction system.

J Am Chem Soc. 2003 Oct 29;125(43):13034-5. doi: 10.1021/ja036425d.

Trapping tyrosinase key active intermediate under turnover.

Dalton Trans. 2009 Sep 7(33):6468-71. doi: 10.1039/b911946a. Epub 2009 Jul 15.

Reactivity of dinuclear copper(II) complexes towards melanoma cells: Correlation with its stability, tyrosinase mimicking and nuclease activity.

J Inorg Biochem. 2015 Aug;149:49-58. doi: 10.1016/j.jinorgbio.2015.05.007. Epub 2015 May 19.

New catalytic model systems of tyrosinase: fine tuning of the reactivity with pyrazole-based N-donor ligands.

Chem Commun (Camb). 2014 Mar 4;50(18):2298-300. doi: 10.1039/c3cc47888b. Epub 2014 Jan 20.

Post-translational His-Cys cross-linkage formation in tyrosinase induced by copper(II)-peroxo species.

J Am Chem Soc. 2011 Feb 9;133(5):1180-3. doi: 10.1021/ja108280w. Epub 2011 Jan 10.

Marigold-like tyrosinase-embedded nanostructures-a nano-in-micro system.

Dalton Trans. 2020 Aug 18;49(32):11329-11335. doi: 10.1039/d0dt02358b.

Structural insights into dioxygen-activating copper enzymes.

Curr Opin Struct Biol. 2006 Dec;16(6):729-35. doi: 10.1016/j.sbi.2006.09.005. Epub 2006 Sep 29.

Tyrosinase kinetics: a semi-quantitative model of the mechanism of oxidation of monohydric and dihydric phenolic substrates.

J Theor Biol. 2000 Mar 7;203(1):1-12. doi: 10.1006/jtbi.1999.1061.

Hydroxylation of phenolic compounds by a peroxodicopper(II) complex: further insight into the mechanism of tyrosinase.

J Am Chem Soc. 2005 Dec 28;127(51):18031-6. doi: 10.1021/ja0544298.

引用本文的文献

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Chem Asian J. 2025 Jun;20(11):e202500123. doi: 10.1002/asia.202500123. Epub 2025 Apr 30.

Copper-Catalyzed Monooxygenation of Phenols: Evidence for a Mononuclear Reaction Mechanism.

Angew Chem Int Ed Engl. 2022 Jun 20;61(25):e202202562. doi: 10.1002/anie.202202562. Epub 2022 Apr 28.

Room temperature stable multitalent: highly reactive and versatile copper guanidine complexes in oxygenation reactions.

J Biol Inorg Chem. 2021 May;26(2-3):249-263. doi: 10.1007/s00775-021-01849-9. Epub 2021 Feb 17.

Exceptional Substrate Diversity in Oxygenation Reactions Catalyzed by a Bis(μ-oxo) Copper Complex.

Chemistry. 2020 Jun 18;26(34):7556-7562. doi: 10.1002/chem.202000664. Epub 2020 May 19.

Directed Hydroxylation of sp and sp C-H Bonds Using Stoichiometric Amounts of Cu and HO.

Inorg Chem. 2019 Jun 3;58(11):7584-7592. doi: 10.1021/acs.inorgchem.9b00901. Epub 2019 May 14.

Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O Model Systems to Organometallic Transformations.

Chem Rev. 2019 Feb 27;119(4):2954-3031. doi: 10.1021/acs.chemrev.8b00368. Epub 2019 Jan 30.

Catalytic mechanism of the tyrosinase reaction toward the Tyr98 residue in the caddie protein.

PLoS Biol. 2018 Dec 31;16(12):e3000077. doi: 10.1371/journal.pbio.3000077. eCollection 2018 Dec.

A bio-inspired synthesis of oxindoles by catalytic aerobic dual C-H functionalization of phenols.

Chem Sci. 2016 Jan 1;7(1):358-369. doi: 10.1039/c5sc02395e. Epub 2015 Oct 6.

Decoding the Mechanism of Intramolecular Cu-Directed Hydroxylation of sp C-H Bonds.

J Org Chem. 2017 Aug 4;82(15):7887-7904. doi: 10.1021/acs.joc.7b01069. Epub 2017 Jul 14.

Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity.

Chem Rev. 2017 Feb 8;117(3):2059-2107. doi: 10.1021/acs.chemrev.6b00636. Epub 2017 Jan 19.