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新型镧系叠氮配合物:水热合成、结构及磁性

Novel lanthanide-azido complexes: hydrothermal syntheses, structures and magnetic properties.

作者信息

Liu Fu-Chen, Zeng Yong-Fei, Zhao Jiong-Peng, Hu Bo-Wen, Hu Xin, Ribas J, Bu Xian-He

机构信息

Department of Chemistry, Nankai University, Tianjin, 300071, China.

出版信息

Dalton Trans. 2009 Mar 28(12):2074-6. doi: 10.1039/b819955h. Epub 2009 Feb 13.

DOI:10.1039/b819955h
PMID:19274282
Abstract

Three new 1D lanthanide-azido complexes, Ln(2)(N(3))(isonic)(2)-(OH)(3)(Hisonic)(H(2)O) (Ln = Gd(III), Eu(III) and Sm(III)), were synthesized by hydrothermal reaction and their magnetic properties were studied.

摘要

通过水热反应合成了三种新型一维镧系叠氮配合物[Ln₂(N₃)(异烟酸)₂(OH)₃(异烟酸)(H₂O)]ₙ(Ln = Gd(III)、Eu(III)和Sm(III)),并对其磁性能进行了研究。

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