6-乙烯辅酶 Q0：利用聚对苯醌修饰电极表面进行 NADH 氧化的电聚合和电催化。
6-Vinyl coenzyme Q0: Electropolymerization and electrocatalysis of NADH oxidation exploiting poly-p-quinone-modified electrode surfaces.
机构信息
Key Laboratory for Advanced Materials and Department of Chemistry, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, PR China.
出版信息
Bioelectrochemistry. 2011 Feb;80(2):128-31. doi: 10.1016/j.bioelechem.2010.07.003. Epub 2010 Jul 18.
6-Vinyl coenzyme Q(0) serves as a convenient starting material for the formation of electropolymerized coenzyme Q(0) on glassy carbon electrodes and the modified electrodes displays electrocatalytic activity toward NADH (β-nicotinamide adenine dinucleotide) oxidation. The detection of NADH was measured by differential pulse voltammetry, which reveals that the peak current is linear to the concentration of NADH within the range of 10-100μM. This would be helpful for the understanding of the interaction between coenzyme Q(0) and NADH in the biological process.
6-乙烯辅酶 Q(0) 可用作在玻碳电极上形成辅酶 Q(0) 电聚合的方便起始材料，并且修饰电极对 NADH（β-烟酰胺腺嘌呤二核苷酸）氧化具有电催化活性。通过差分脉冲伏安法测量 NADH 的检测，表明在 10-100μM 范围内峰电流与 NADH 的浓度呈线性关系。这有助于理解辅酶 Q(0)与 NADH 在生物过程中的相互作用。
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