A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninskiy pr., Moscow 119991, Russia.
Inorg Chem. 2010 Sep 6;49(17):7611-3. doi: 10.1021/ic100951y.
Neptunium(VI) benzoate with mu(3)-OH(-) has been isolated and studied by the X-ray method. The main structural motive in the crystal is corrugated ribbons (NpO(2))(2)(mu(3)-OH)(2)(C(7)H(5)O(2))(2) extended along the c axes in which three neptunium pentagonal bipyramids are linked through the mu(3)-OH(-) ligand. The benzoate ions are arranged at both sides of the ribbons, and each anion binds two adjacent NpO(2). The water molecules are arranged in the channels along the c axis.
六价铀苯甲酸酯与 μ(3)-OH(-)通过 X 射线方法被分离并研究。晶体中的主要结构基元是沿 c 轴延伸的波纹状带状物(NpO(2))(2)(μ(3)-OH)(2)(C(7)H(5)O(2))(2)，其中三个五边形双锥铀通过 μ(3)-OH(-)配体连接。苯甲酸离子排列在带状物的两侧，每个阴离子与两个相邻的 NpO(2)结合。水分子沿 c 轴排列在通道中。
