Institut für Physikalische Chemie, TU Bergakademie Freiberg, Leipziger Strasse 29, D-09596 Freiberg, Germany.
J Am Chem Soc. 2010 Aug 18;132(32):10978-81. doi: 10.1021/ja1028777.
A simple two-component procedure was developed to synthesize not only classical zinc-based IRMOFs represented by MOF-5 but also the cobalt and beryllium homologues of this most prominent MOF. The procedure is the first manifestation of mirroring the IRMOF series with other metal centers taken from main-group as well as transition-metal elements. Because of the existence of many suitable precursors, the procedure promises the generation of a large number of IRMOF homologues. Since the IRMOF series together with the MIL series is the MOF group with the largest number of representatives, the possibility of choosing the metal centers of the secondary building units from an extended set will tremendously expand the number of obtainable structures in a predictive, crystal-engineering-type way. Use of metal centers other than zinc will allow the addition of new features to the existing IRMOF structures, such as magnetic properties in the example of cobalt.
一种简单的双组分方法被开发出来，不仅可以合成经典的基于锌的 IRMOFs，如 MOF-5，还可以合成这个最著名的 MOF 的钴和铍同系物。该方法是首次用主族和过渡金属元素的其他金属中心来镜像 IRMOF 系列。由于存在许多合适的前体，该方法有望生成大量的 IRMOF 同系物。由于 IRMOF 系列与 MIL 系列一起是具有最多代表的 MOF 基团，因此从扩展的集合中选择次级结构单元的金属中心的可能性将以可预测的、晶体工程类型的方式极大地扩展可获得结构的数量。使用除锌以外的金属中心将允许在现有的 IRMOF 结构中添加新的特性，例如钴的磁性。
