Max-Planck-Institut für Chemische Physik fester Stoffe, Dresden 01187, Germany.
J Am Chem Soc. 2010 Aug 18;132(32):10984-5. doi: 10.1021/ja104197c.
BaGe(5) constitutes a new type of intermetallic clathrate obtained by decomposition of clathrate-I Ba(8)Ge(43)(3) at low temperatures. The crystal structure consists of characteristic layers interconnected by covalent bonds. BaGe(5) is a semiconducting Zintl phase.
BaGe(5) 是一种新型的金属互化物，由低温下笼型化合物-I Ba(8)Ge(43)(3) 的分解得到。该晶体结构由共价键连接的特征层组成。BaGe(5) 是一种半导体 Zintl 相。
