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Reversal of the regiochemistry in the rhodium-catalyzed [4+3] cycloaddition between vinyldiazoacetates and dienes.
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D2-symmetric dirhodium catalyst derived from a 1,2,2-triarylcyclopropanecarboxylate ligand: design, synthesis and application.
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Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations.
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Assembly of Complex 1,4-Cycloheptadienes by (4+3) Cycloaddition of Rhodium(II) and Gold(I) Non-Acceptor Carbenes.
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Catalytic asymmetric cycloaddition reactions of enoldiazo compounds.
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Cycloaddition reactions of enoldiazo compounds.
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Asymmetric Syntheses of the Flavonoid Diels-Alder Natural Products Sanggenons C and O.
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Application of donor/acceptor-carbenoids to the synthesis of natural products.
Chem Soc Rev. 2009 Nov;38(11):3061-71. doi: 10.1039/b901170f. Epub 2009 Sep 30.
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Computational study on the selectivity of donor/acceptor-substituted rhodium carbenoids.
J Org Chem. 2009 Sep 4;74(17):6555-63. doi: 10.1021/jo9009968.
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Asymmetric [4+3] cycloadditions between benzofuranyldiazoacetates and dienes: formal synthesis of (+)-frondosin B.
Org Lett. 2008 Feb 21;10(4):573-6. doi: 10.1021/ol702844g. Epub 2008 Jan 24.
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Asymmetric synthesis of tropanes by rhodium-catalyzed [4 + 3] cycloaddition.
J Am Chem Soc. 2007 Aug 29;129(34):10312-3. doi: 10.1021/ja072936e. Epub 2007 Aug 8.
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Modern synthetic efforts toward biologically active terpenes.
Nat Chem Biol. 2007 Jul;3(7):396-407. doi: 10.1038/nchembio.2007.1.
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