National Laboratory for Molecular Sciences, Institute of Chemistry and Graduate School, Chinese Academy of Sciences, Beijing, 100190, PR China.
Org Lett. 2010 Sep 17;12(18):4078-81. doi: 10.1021/ol1014569.
A macrocycle and a rotaxane were constructed by virtue of the thiol-yne click reaction under the irradiation of light in high yield, which can proceed at ambient temperature and humidity under an air atmosphere. Two disulfide macrocycles were synthesized through a simple dithiol coupling reaction, which exhibited high stability and a weak assembly interaction with a dialkylammonium ion.
通过在光照下的硫醇-炔点击反应，以高产率构建了大环和轮烷，其可以在环境温度和湿度下在空气气氛中进行。通过简单的二硫醇偶联反应合成了两个二硫键大环，其表现出高稳定性和与二烷基铵离子的弱组装相互作用。
