Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai, Miyagi 980-8578, Japan.
Chem Commun (Camb). 2011 Jan 7;47(1):271-3. doi: 10.1039/c0cc02031a. Epub 2010 Aug 17.
A new D(2)A-type charge-transfer three-dimensional network with a charge distribution of [{Ru(2)}(δ+)-(BTDA-TCNQ(2δ-))-{Ru(2)}(δ+)] where δ ≈ 1, which exhibits a sudden decrease in electronic resistance, formed from the assembly of a paddlewheel diruthenium(II, II) complex ([Ru(2)]) as a donor (D) and bis(1,2,5-thiadiazolo)tetracyanoquinodimethane (BTDA-TCNQ) as an acceptor (A).
一个新的 D(2)A 型电荷转移三维网络，具有 [{Ru(2)}(δ+)-(BTDA-TCNQ(2δ-))-{Ru(2)}(δ+)] 的电荷分布，其中 δ ≈ 1，它由一个桨轮二钌(II, II) 配合物 ([Ru(2)]) 作为供体 (D) 和双(1,2,5-噻二唑)四氰基醌二甲烷 (BTDA-TCNQ) 作为受体 (A) 的组装形成，表现出电子电阻的突然下降。
