Interdisciplinary School of Green Energy, Ulsan National Institute of Science and Technology/UNIST, Ulsan 689-798, Korea.
Chem Commun (Camb). 2010 Sep 28;46(36):6795-7. doi: 10.1039/c0cc02522d. Epub 2010 Aug 20.
We report on the evolution of a hollow sphere secondary structure of spherical nanoparticles by a solubilization-reprecipitation mechanism based on the difference of solubility products (K(sp)) of two different precipitates. Carbon-coated nanoparticles of olivine structure LiFePO(4) served as the primary nano-blocks to build the secondary nano-architecture.
我们报告了一种通过基于两种不同沉淀物的溶度积(Ksp)差异的溶解-再沉淀机制来实现空心球形纳米粒子的二次结构演变。橄榄石结构的 LiFePO4 碳包覆纳米粒子作为初级纳米块来构建二次纳米结构。