Monash University, Clayton, Victoria 3800, Australia.
Chem Commun (Camb). 2010 Sep 28;46(36):6789-91. doi: 10.1039/c0cc02289f. Epub 2010 Aug 23.
The C-C bond fragmentation of carbocycles has been developed as a new method for the divergent synthesis of dendrimers. The scope of this reaction was examined with the preparation of six first generation dendrimers from structurally diverse and readily available fragmentation precursors. By pairing the fragmentation with a thio-Michael reaction, the preparation of a [G4]-ene(24) dendrimer has been achieved.
碳环的 C-C 键断裂已被开发为树枝状大分子发散合成的新方法。通过使用结构多样且易于获得的断裂前体制备六种第一代树枝状大分子，考察了该反应的范围。通过将断裂与硫迈克尔加成反应偶联，实现了[G4]-烯（24）树枝状大分子的制备。
