Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Nagoya, 464-8602, Japan.
Chem Commun (Camb). 2011 Jan 7;47(1):170-2. doi: 10.1039/c0cc02221g. Epub 2010 Aug 23.
Apo-ferritin (apo-Fr) mutants are used as scaffolds to accommodate palladium (allyl) complexes. Various coordination arrangements of the Pd complexes are achieved by adjusting the positions of cysteine and histidine residues on the interior surface of the apo-Fr cage.
载铁蛋白(apo-Fr)突变体被用作支架来容纳钯(烯丙基)配合物。通过调整apo-Fr 笼体内表面上半胱氨酸和组氨酸残基的位置,实现了 Pd 配合物的各种配位排列。