α-芳氧基醛：作为 NHC 催化氧化还原转化中α-卤代醛替代品的范围和限制。
α-Aroyloxyaldehydes: scope and limitations as alternatives to α-haloaldehydes for NHC-catalysed redox transformations.
机构信息
EaStCHEM, School of Chemistry, University of St Andrews, North Haugh, St Andrews, KY16 9ST, UK.
出版信息
Chem Commun (Camb). 2011 Jan 7;47(1):373-5. doi: 10.1039/c0cc02456b. Epub 2010 Aug 23.
PMID:20730235
Abstract
α-Aroyloxyaldehydes are readily prepared bench stable synthetic intermediates. Their ability to act as α-haloaldehyde surrogates for NHC-promoted redox esterifications and in [4+2] cycloadditions is described.
摘要
α-Aroyloxyaldehydes 是易于制备的、稳定的合成中间体。它们能够作为 NHC 促进的氧化还原酯化反应和 [4+2] 环加成反应中的 α-卤代醛替代品，这一点得到了描述。
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