烯丙基硫醚的 Johnson-Claisen 重排中的非环立体控制。
Exopericyclic stereocontrol in Johnson-Claisen rearrangements of allylic sulfides.
机构信息
Department of Chemistry, Imperial College London, South Kensington Campus, London, SW7 2AZ, UK.
出版信息
Chem Commun (Camb). 2010 Oct 7;46(37):6932-4. doi: 10.1039/c0cc01039a. Epub 2010 Aug 23.
PMID:20733969
Abstract
A study of the effects of exopericyclic stereocentres on the stereoselectivity of Johnson-Claisen rearrangements of thioether-containing allylic alcohols shows that selectivity is highly dependent upon allylic substitution patterns.
摘要
对含有硫醚的烯丙醇的 Johnson-Claisen 重排中环外立体中心对立体选择性的影响的研究表明，选择性高度依赖于烯丙基取代模式。
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