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基于十八烷基三氯硅烷和二氧化硅纳米粒子的超疏水仿生表面的简易制备。

Facile preparation of superhydrophobic biomimetic surface based on octadecyltrichlorosilane and silica nanoparticles.

机构信息

Department of Chemical Engineering and Processing, College of Chemical and Materials Engineering, WenZhou University, WenZhou, ZheJiang 325000, P. R. China.

出版信息

ACS Appl Mater Interfaces. 2010 Aug;2(8):2393-8. doi: 10.1021/am1004046.

Abstract

The present paper describes the simple and low-cost process for the production of a superhydrophobic surface with micronano hierarchical structure from the chemisorptions of SiO(2) nanoparticles onto polymerized n-octadecylsilane. The process was carried out under ambient conditions without the use of expensive equipment. The as-prepared micronano-binary films exhibited a very high contact angle of 179.9 degrees and a low contact hysteresis of 2.5 degrees . On the basis of the results of the characterization techniques, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR) and contact angle (CA) measurements, a formation mechnism of the superhydrophobic micronano structure was proposed. Drop impact experiments on the modified-glass substrate showed that the as-prepared films possess a high-impalement threshold.

摘要

本文描述了一种简单且低成本的方法,通过硅烷化试剂在聚合物表面上化学吸附二氧化硅纳米粒子,制备具有微米-纳米分级结构的超疏水表面。该过程在环境条件下进行,无需使用昂贵的设备。所制备的微米-纳米二元薄膜表现出非常高的接触角 179.9 度和低的接触滞后 2.5 度。基于各种表征技术(SEM、FT-IR 和 CA 测量)的结果,提出了超疏水微米-纳米结构的形成机理。在改性玻璃基底上进行的液滴冲击实验表明,所制备的薄膜具有较高的冲击阈值。

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