Department of Chemical Engineering and Processing, College of Chemical and Materials Engineering, WenZhou University, WenZhou, ZheJiang 325000, P. R. China.
ACS Appl Mater Interfaces. 2010 Aug;2(8):2393-8. doi: 10.1021/am1004046.
The present paper describes the simple and low-cost process for the production of a superhydrophobic surface with micronano hierarchical structure from the chemisorptions of SiO(2) nanoparticles onto polymerized n-octadecylsilane. The process was carried out under ambient conditions without the use of expensive equipment. The as-prepared micronano-binary films exhibited a very high contact angle of 179.9 degrees and a low contact hysteresis of 2.5 degrees . On the basis of the results of the characterization techniques, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR) and contact angle (CA) measurements, a formation mechnism of the superhydrophobic micronano structure was proposed. Drop impact experiments on the modified-glass substrate showed that the as-prepared films possess a high-impalement threshold.
本文描述了一种简单且低成本的方法,通过硅烷化试剂在聚合物表面上化学吸附二氧化硅纳米粒子,制备具有微米-纳米分级结构的超疏水表面。该过程在环境条件下进行,无需使用昂贵的设备。所制备的微米-纳米二元薄膜表现出非常高的接触角 179.9 度和低的接触滞后 2.5 度。基于各种表征技术(SEM、FT-IR 和 CA 测量)的结果,提出了超疏水微米-纳米结构的形成机理。在改性玻璃基底上进行的液滴冲击实验表明,所制备的薄膜具有较高的冲击阈值。