Department of Applied Chemistry and Biochemistry, Kumamoto University, 2-39-1 Kurokami, Kumamoto 860-8555, Japan.
Chem Commun (Camb). 2010 Oct 14;46(38):7208-10. doi: 10.1039/c0cc01190h. Epub 2010 Aug 25.
We propose a new strategy for fabrication of a phase-separated bicontinuous system composed of low-molecular donor and acceptor that is built up through coordination-based orientation of pyridylated fullerene on a π-conjugated zinc-porphyrin J-type assembly. This complex system exhibits extremely efficient and switchable fluorescence quenching.
我们提出了一种新的策略,用于制造由低分子给体和受体组成的相分离双连续体系,该体系是通过在π-共轭锌卟啉 J 型组装体上的吡啶化富勒烯的基于配位的取向构建而成。这个复杂体系表现出非常高效和可切换的荧光猝灭。