Agricultural Chemistry Department, Universidad Autónoma de Madrid, Madrid, Spain.
J Sci Food Agric. 2010 Dec;90(15):2633-40. doi: 10.1002/jsfa.4132.
Synthetic Fe chelates are commonly used to overcome Fe deficiencies in crops, but most of them are scarcely biodegradable. Iminodisuccinic acid (IDHA) is a biodegradable chelating agent that is currently being evaluated as an alternative to EDTA. In this work, the efficacy of the foliar application of IDHA/Fe(3+) to soybean chlorotic plants under controlled conditions was studied, testing the influence of the adjuvant used and of the plant nutritional status.
When IDHA/Fe(3+) was applied to soybean plants with severe Fe chlorosis and the foliar sprays were the sole source of Fe, this chelate behaved similarly to the EDTA/Fe(3+) and the recovery of the plants was slight in both cases. The same chelates were tested when foliar sprays were an additional source of Fe for mildly chlorotic plants, which were also being supplied with low concentrations of Fe applied to the nutrient solution. Then, plant recovery was appreciable in all cases, and the IDHA/Fe(3+) was as effective as EDTA/Fe(3+). Among the adjuvants studied, a urea-based product was the only one that did not damage the leaf surface and that could improve the efficiency of IDHA/Fe(3+) up tp the level of EDTA/Fe(3+).
Thus, it was concluded the foliar application of IDHA/Fe(3+) can be an environmentally friendly alternative to the non-biodegradable chelate EDTA/Fe(3+) when the appropriate adjuvant is used.
合成 Fe 螯合物常用于克服作物中的 Fe 缺乏症,但大多数都不易生物降解。亚氨基二琥珀酸(IDHA)是一种可生物降解的螯合剂,目前正在被评估作为 EDTA 的替代品。在这项工作中,在受控条件下研究了叶面施用 IDHA/Fe(3+)对大豆黄化植物的效果,测试了所用助剂和植物营养状况的影响。
当 IDHA/Fe(3+)施用于严重缺铁的大豆植物,并且叶面喷雾是 Fe 的唯一来源时,这种螯合物的行为与 EDTA/Fe(3+)相似,两种情况下植物的恢复都很轻微。当叶面喷雾是轻度缺铁植物的额外 Fe 来源,并且也在营养液中施加低浓度的 Fe 时,测试了相同的螯合物。然后,在所有情况下,植物的恢复都很明显,IDHA/Fe(3+)的效果与 EDTA/Fe(3+)一样好。在所研究的助剂中,只有一种基于尿素的产品不会损坏叶片表面,并且可以将 IDHA/Fe(3+)的效率提高到 EDTA/Fe(3+)的水平。
因此,当使用适当的助剂时,叶面施用 IDHA/Fe(3+)可以成为不可生物降解的螯合物 EDTA/Fe(3+)的环保替代品。