内消旋双官能化三苯并三嗪并[1,2-b:2',1'-e][1,3,5]三嗪的合成和光学拆分。
Synthesis and optical resolution of inherently chiral difunctionalized tribenzotriquinacenes.
机构信息
State Key Laboratory of Applied Organic Chemistry and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, People's Republic of China.
出版信息
J Org Chem. 2010 Oct 1;75(19):6704-7. doi: 10.1021/jo101106k.
The synthesis of several inherently chiral tribenzotriquinacenes (TBTQs) bearing one single mono- or difunctionalized aromatic nucleus and the optical resolution of one of these derivatives, a TBTQ-based salicylic acid (11), are described for the first time. Efficient access to enantiopure, inherently chiral tribenzotriquinacenes may lay a foundation for studies of novel container compounds, supramolecular aggregation, chiral recognition, and asymmetric catalysis.
首次描述了几种带有单个单官能化或双官能化芳核的固有手性三苯并三嗪喹吖啶酮（TBTQ）的合成以及这些衍生物之一的基于 TBTQ 的水杨酸（11）的光学拆分。高效获得对映纯固有手性三苯并三嗪喹吖啶酮可能为新型容器化合物、超分子聚集、手性识别和不对称催化的研究奠定基础。
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