Departamento de Química Orgánica, Facultad de Química, Universidad de Castilla-La Mancha, 13071 Ciudad Real, Spain.
Nanoscale. 2010 Aug;2(8):1390-400. doi: 10.1039/c0nr00085j. Epub 2010 Jun 4.
The combination of different nanomaterials such as metallic nanoparticles and carbon nanostructures in a new hybrid material should give rise to interesting properties that combine the advantages of each of the nanocomponents. This review highlights the latest advances in the synthetic design of these hybrid materials where carbon nanostructures act as supports as well as stabilizing agents for very reactive metallic nanoparticles. The striking applications of Pd nanoparticles anchored on the surface of carbon nanostructures in C-C coupling chemistry are analyzed. Special emphasis is placed on the stability of these materials, which is linked to their recyclability. Numerous examples are given that involve the use of these catalysts in Heck, Suzuki and Sonogashira coupling reactions.
将不同的纳米材料（如金属纳米粒子和碳纳米结构）组合在一种新的混合材料中，应该会产生有趣的性质，结合每种纳米组件的优点。这篇综述强调了这些混合材料的合成设计的最新进展，其中碳纳米结构既作为载体，又作为非常活泼的金属纳米粒子的稳定剂。分析了锚定在碳纳米结构表面的 Pd 纳米粒子在 C-C 偶联化学中的引人注目的应用。特别强调了这些材料的稳定性，这与其可回收性有关。给出了许多涉及这些催化剂在 Heck、Suzuki 和 Sonogashira 偶联反应中应用的例子。
