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SBA - 15负载钯金属催化剂作为纳米反应器在碳 - 碳偶联反应中的应用

Applications of SBA-15 supported Pd metal catalysts as nanoreactors in C-C coupling reactions.

作者信息

Mohammadi Ziarani Ghodsi, Rohani Sahar, Ziarati Abolfazl, Badiei Alireza

机构信息

Department of Chemistry, Faculty of Science, University of Alzahra Tehran Iran

School of Chemistry, College of Science, University of Tehran Tehran Iran.

出版信息

RSC Adv. 2018 Dec 7;8(71):41048-41100. doi: 10.1039/c8ra09038f. eCollection 2018 Dec 4.

DOI:10.1039/c8ra09038f
PMID:35557901
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9091621/
Abstract

Nanoreactors are material structures with engineered internal cavities which create exclusive confined nanoscale surroundings for chemical reactions. The cavities of mesoporous silica SBA-15 can be used as nanoreactors for incorporating catalytic species such as metal nanoparticles, complexes Since SBA-15 silica has a neutral framework, organic functional groups and heteroatoms have been embedded by direct or post-synthesis approaches in order to modify their functionality. Palladium is the most used transition metal for C-C bond formations. Because of the great importance of C-C coupling reactions, this review article aims at providing a deep insight into the state of art in the field of the synthesis and the application of mesoporous SBA-15 silica-supported Pd catalysts in C-C coupling transformations. In most cases, synthesis and modification of the catalyst, time and yield of reactions, recyclability and leaching of the Pd species from the SBA-15 support are discussed to reveal the role of SBA-15 in C-C coupling reactions.

摘要

纳米反应器是具有工程化内部空腔的材料结构，这些空腔为化学反应创造了独特的受限纳米级环境。介孔二氧化硅SBA-15的空腔可作为纳米反应器，用于掺入催化物种，如金属纳米颗粒、配合物。由于SBA-15二氧化硅具有中性骨架，已通过直接或后合成方法嵌入有机官能团和杂原子，以改变其功能。钯是用于形成碳-碳键最常用的过渡金属。由于碳-碳偶联反应非常重要，这篇综述文章旨在深入洞察介孔SBA-15二氧化硅负载钯催化剂在碳-碳偶联转化中的合成与应用领域的现状。在大多数情况下，会讨论催化剂的合成与改性、反应时间和产率、钯物种从SBA-15载体的可回收性和浸出情况，以揭示SBA-15在碳-碳偶联反应中的作用。

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