Ono Masateru, Imao Masae, Miyahara Kazumoto
School of Agriculture, Tokai University, Aso, Kumamoto 869-1404, Japan.
Chem Pharm Bull (Tokyo). 2010 Sep;58(9):1232-5. doi: 10.1248/cpb.58.1232.
Two new glycosidic acids, quamoclinic acids G and H, were isolated from the glycosidic acid fraction afforded by alkaline hydrolysis of the ether-insoluble resin glycoside (convolvulin) fraction from the seeds of Quamoclit pennata BOJER. Both compounds are the first examples of bisdesmosides of glycosidic acid having the sugar linkages at C-3 of 3,11-dihydroxytetradecanoic acid (ipurolic acid) as well as at its C-11.
从圆叶牵牛(Quamoclit pennata BOJER)种子的醚不溶性树脂糖苷(旋花素)部分经碱性水解得到的糖苷酸部分中分离出两种新的糖苷酸,即月光花酸G和H。这两种化合物都是糖苷酸双糖苷的首例,其糖键连接在3,11 - 二羟基十四烷酸(异普洛酸)的C - 3以及C - 11处。