Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China.
Inorg Chem. 2010 Oct 4;49(19):8647-9. doi: 10.1021/ic100558x.
The novel porous 3D metal-organic framework synthesized from fluorenone-2,7-dicarboxylate contains zinc-glycolate-carboxylate layers in which the unique hexagonal prismatic [Zn(6)(OCH(2)CH(2)O)(6)] clusters are connected by planar [Zn(3)(OCH(2)CH(2)O)(COO)(2)] motifs; the pore surface is furnished with carbonyl groups and open metal sites.
新型多孔 3D 金属有机骨架由芴酮-2,7-二羧酸合成，其中包含锌-乙醇酸-羧酸层，独特的六方棱柱形 [Zn(6)(OCH(2)CH(2)O)(6)] 簇通过平面 [Zn(3)(OCH(2)CH(2)O)(COO)(2)] 基元连接；孔表面配备了羰基和开放的金属位。
