Beijing National Laboratory of Molecular Sciences, College of Chemistry, Peking University, Beijing 100871, China.
J Am Chem Soc. 2010 Oct 6;132(39):13590-1. doi: 10.1021/ja105762n.
A Pd-catalyzed three-component reaction of N-tosylhydrazone, terminal alkyne, and aryl halide follows a mechanism involving a sequence of Pd carbene migratory insertion-transmetalation-reductive elimination, leading to the formation of one sp(2)-sp(3) C-C bond and one sp-sp(3) C-C bond.
Pd 催化的 N-对甲苯磺酰腙、末端炔烃和芳基卤化物的三组分反应遵循一个涉及 Pd 卡宾迁移插入-转金属化-还原消除的序列的机理，导致一个 sp(2)-sp(3) C-C 键和一个 sp-sp(3) C-C 键的形成。
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