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并五苯二吲哚基喹喔啉:具有磷酸盐选择性的双信号阴离子受体。

Tetrathiafulvalene diindolylquinoxaline: a dual signaling anion receptor with phosphate selectivity.

机构信息

Department of Chemistry and Biochemistry and Institute for Cellular and Molecular Biology, The University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712-0156, USA.

出版信息

Chem Commun (Camb). 2010 Nov 7;46(41):7745-7. doi: 10.1039/c0cc02934c. Epub 2010 Sep 20.

DOI:10.1039/c0cc02934c
PMID:20856940
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3123379/
Abstract

Incorporation of tetrathiafulvalene into the backbone of a known neutral phosphate receptor, diindolylquinoxaline, yields a dual optical-electrochemical chemosensor for dihydrogen phosphate that functions in dichloromethane. This system shows selectivity for dihydrogen phosphate over other small anions and can be used to detect the presence of this analyte via fluorescence quenching or cyclic voltammetry.

摘要

将四硫富瓦烯引入已知中性磷酸受体二吲哚并喹喔啉的骨架中,得到了一种在二氯甲烷中用于检测磷酸二氢盐的双光电化学化学传感器。该体系对磷酸二氢盐具有选择性,可用于通过荧光猝灭或循环伏安法检测该分析物的存在。

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本文引用的文献

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Pyrazino[2.3-g]quinoxaline-bridged indole-based building blocks: design, synthesis, anion-binding properties, and phosphate-directed assembly in the solid state.吡嗪并[2,3-g]喹喔啉桥联吲哚基构筑块:设计、合成、阴离子结合性能及固态中磷酸酯导向组装。
Chemistry. 2010 Apr 19;16(15):4639-49. doi: 10.1002/chem.200903188. Epub 2010 Mar 23.
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Polyaza cryptand receptor selective for dihydrogen phosphate.多氮杂环 cryptand 受体对二氢磷酸盐具有选择性。
J Org Chem. 2009 Nov 20;74(22):8638-46. doi: 10.1021/jo901742d.
3
Tetrathiafulvalene (TTF) derivatives: key building-blocks for switchable processes.四硫富瓦烯(TTF)衍生物:可切换过程的关键构建模块。
Chem Commun (Camb). 2009 May 7(17):2245-69. doi: 10.1039/b818607n. Epub 2009 Mar 19.
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1,3-Diindolylureas: high affinity dihydrogen phosphate receptors.1,3-二吲哚基脲:高亲和力磷酸二氢根受体。
Chem Commun (Camb). 2008 Jul 14(26):3007-9. doi: 10.1039/b806238b. Epub 2008 May 29.
5
Synthetic model of the phosphate binding protein: solid-state structure and solution-phase anion binding properties of a large oligopyrrolic macrocycle.磷酸结合蛋白的合成模型:一种大型寡聚吡咯大环化合物的固态结构与溶液相阴离子结合特性
J Org Chem. 2007 Sep 14;72(19):7244-52. doi: 10.1021/jo071106g. Epub 2007 Aug 18.
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Supramolecular chemistry approach to the design of a high-resolution sensor array for multianion detection in water.用于水中多阴离子检测的高分辨率传感器阵列设计的超分子化学方法。
J Am Chem Soc. 2007 Jun 20;129(24):7538-44. doi: 10.1021/ja0704784. Epub 2007 May 27.
7
An experimental and computational study on intramolecular charge transfer: a tetrathiafulvalene-fused dipyridophenazine molecule.分子内电荷转移的实验与计算研究:一种四硫富瓦烯稠合的二吡啶并菲嗪分子
Chemistry. 2007;13(13):3804-12. doi: 10.1002/chem.200601561.
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