Department of Chemistry and Biochemistry and Institute for Cellular and Molecular Biology, The University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712-0156, USA.
Chem Commun (Camb). 2010 Nov 7;46(41):7745-7. doi: 10.1039/c0cc02934c. Epub 2010 Sep 20.
Incorporation of tetrathiafulvalene into the backbone of a known neutral phosphate receptor, diindolylquinoxaline, yields a dual optical-electrochemical chemosensor for dihydrogen phosphate that functions in dichloromethane. This system shows selectivity for dihydrogen phosphate over other small anions and can be used to detect the presence of this analyte via fluorescence quenching or cyclic voltammetry.
将四硫富瓦烯引入已知中性磷酸受体二吲哚并喹喔啉的骨架中,得到了一种在二氯甲烷中用于检测磷酸二氢盐的双光电化学化学传感器。该体系对磷酸二氢盐具有选择性,可用于通过荧光猝灭或循环伏安法检测该分析物的存在。