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从流动性的空间相关性分析玻璃质体中的动力学非均匀性。

Analysis of dynamic heterogeneity in a glass former from the spatial correlations of mobility.

机构信息

Centre for Condensed Matter Theory, Department of Physics, Indian Institute of Science, Bangalore, 560012, India.

出版信息

Phys Rev Lett. 2010 Jul 2;105(1):015701. doi: 10.1103/PhysRevLett.105.015701. Epub 2010 Jul 1.

DOI:10.1103/PhysRevLett.105.015701
PMID:20867463
Abstract

The growth of characteristic length scales associated with dynamic heterogeneity in glass-forming liquids is investigated in an extensive computational study of a four-point, time-dependent structure factor defined from spatial correlations of mobility, for a model liquid for system sizes extending up to 351 232 particles, in constant-energy and constant-temperature ensembles. Our estimates for dynamic correlation lengths and susceptibilities are consistent with previous results from finite size scaling. We find scaling exponents that are inconsistent with predictions from inhomogeneous mode coupling theory and a recent simulation confirmation of these predictions.

摘要

我们对一个四点时变结构因子进行了广泛的计算研究,该结构因子源自模型液体中迁移率的空间关联,用于模拟能量和温度固定的体系大小可达 351232 个粒子的情况。我们对动态相关长度和磁化率的估计与之前的有限尺寸标度结果一致。我们发现的标度指数与非均匀模态耦合理论的预测以及最近对这些预测的模拟验证结果不一致。

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Phys Rev Lett. 2010 Jul 2;105(1):015701. doi: 10.1103/PhysRevLett.105.015701. Epub 2010 Jul 1.
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引用本文的文献

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2
Dynamical heterogeneity in active glasses is inherently different from its equilibrium behavior.活性玻璃态物质中的动力学非均匀性与其平衡行为本质上不同。
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The relationship of dynamical heterogeneity to the Adam-Gibbs and random first-order transition theories of glass formation.
动力学非均匀性与玻璃形成的 Adam-Gibbs 和随机一级相变理论的关系。
J Chem Phys. 2013 Mar 28;138(12):12A541. doi: 10.1063/1.4790138.