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切冰:纳米线重结。

Cutting ice: nanowire regelation.

机构信息

Department of Physics, Tampere University of Technology, PO Box 692, FI-33101 Tampere, Finland.

出版信息

Phys Rev Lett. 2010 Aug 20;105(8):086102. doi: 10.1103/PhysRevLett.105.086102. Epub 2010 Aug 19.

Abstract

Even below its normal melting temperature, ice melts when subjected to high pressure and refreezes once the pressure is lifted. A classic demonstration of this regelation phenomenon is the passing of a thin wire through a block of ice when sufficient force is exerted. Here we present a molecular-dynamics study of a nanowire cutting through ice to unravel the molecular level mechanisms responsible for regelation. In particular, we show that the transition from a stationary to a moving wire due to increased driving force changes from symmetric and continuous to asymmetric and discontinuous as a hydrophilic wire is replaced by a hydrophobic one. This is explained at the molecular level in terms of the wetting properties of the wire.

摘要

即使在其正常熔点以下,冰在受到高压时也会融化,一旦压力解除就会再次结冰。这种再结晶现象的一个经典例子是,当施加足够的力时,一根细金属丝穿过冰块。在这里,我们通过分子动力学研究了纳米线切割冰的过程,以揭示导致再结晶的分子水平机制。特别是,我们表明,由于驱动力的增加,从静止到运动的金属丝的转变从对称连续变为非对称不连续,因为亲水金属丝被疏水金属丝取代。这可以用金属丝的润湿性来解释。

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