在结构明确的芳基-Cu(III)-卤化物物种中，酸触发芳基-卤化物还原消除的分子机制。
Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu(III)-halide species.
机构信息
Departament de Química, Universitat de Girona, Campus de Montilivi, Girona, E-17071, Catalonia, Spain.
出版信息
Dalton Trans. 2010 Nov 21;39(43):10458-63. doi: 10.1039/c0dt00284d. Epub 2010 Oct 1.
PMID:20886163
Abstract
Well-defined aryl-Cu(III)-halide species undergo reductive elimination upon acid addition resulting in the formation of strong aryl-halide bonds. The computationally studied mechanism points towards ligand protonation as the rate-determining step, in agreement with previous experimental data.
摘要
定义明确的芳基-Cu(III)-卤化物物种在酸的加入下发生还原消除反应，从而形成强的芳基-卤键。理论计算研究的反应机理表明配体质子化是速率决定步骤，这与先前的实验数据一致。
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