用电喷雾质谱法测定相对路易斯酸金属三氟酸盐的碱性。
Relative basicities toward metal triflates Lewis acids by electrospray mass spectrometry.
机构信息
Laboratoire de Chimie des Molécules Bioactives et des Arômes (UMR CNRS 6001) Institut de Chimie de Nice (FR CNRS 3037), Université de Nice-Sophia Antipolis, Parc Valrose, 06108 NICE Cedex 2, France.
出版信息
Chem Commun (Camb). 2010 Nov 28;46(44):8472-4. doi: 10.1039/c0cc02673e. Epub 2010 Oct 6.
PMID:20927451
Abstract
The relative Lewis basicity of a series of phosphoryl compounds toward cations M(n+)(OTf)(n-1) derived from triflate salts, M(OTf)(n), is ranked using electrospray mass spectrometry according to competitive adduct formation.
摘要
采用电喷雾质谱法，根据竞争加合物形成，对一系列磷酸酯化合物与源自三氟甲磺酸盐的阳离子 M(n+)(OTf)(n-1)（M(OTf)(n)）的相对路易斯碱度进行排序。
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