Department of Urban Engineering, School of Engineering, The University of Tokyo, Hongo 7-3-1, Bunkyo-ku, Tokyo 113-8656, Japan.
Int J Environ Res Public Health. 2010 Sep;7(9):3489-98. doi: 10.3390/ijerph7093489. Epub 2010 Sep 17.
The irreversible removal of acetaldehyde from indoor air via a chemical reaction with amino acids was investigated. To compare effectiveness, five types of amino acid (glycine, l-lysine, l-methionine, l-cysteine, and l-cystine) were used as the reactants. First, acetaldehyde-laden air was introduced into aqueous solutions of each amino acid and the removal abilities were compared. Among the five amino acids, l-cysteine solution showed much higher removal efficiency, while the other amino acids solutions didn't show any significant differences from the removal efficiency of water used as a control. Next, as a test of the removal abilities of acetaldehyde by semi-solid l-cysteine, a gel containing l-cysteine solution was put in a fluororesin bag filled with acetaldehyde gas, and the change of acetaldehyde concentration was measured. The l-cysteine-containing gel removed 80% of the acetaldehyde in the air within 24 hours. The removal ability likely depended on the unique reaction whereby acetaldehyde and l-cysteine rapidly produce 2-methylthiazolidine-4-carboxylic acid. These results suggested that the reaction between acetaldehyde and l-cysteine has possibilities for irreversibly removing toxic acetaldehyde from indoor air.
研究了通过与氨基酸的化学反应不可逆地去除室内空气中的乙醛。为了比较效果,使用了五种类型的氨基酸(甘氨酸、L-赖氨酸、L-蛋氨酸、L-半胱氨酸和 L-胱氨酸)作为反应物。首先,将含有乙醛的空气引入每种氨基酸的水溶液中,并比较去除能力。在这五种氨基酸中,L-半胱氨酸溶液显示出更高的去除效率,而其他氨基酸溶液与用作对照的水的去除效率没有任何显著差异。接下来,作为对半固态 L-半胱氨酸去除乙醛能力的测试,将含有 L-半胱氨酸溶液的凝胶放入充满乙醛气体的氟树脂袋中,测量乙醛浓度的变化。含 L-半胱氨酸的凝胶在 24 小时内去除了空气中 80%的乙醛。去除能力可能取决于乙醛和 L-半胱氨酸迅速产生 2-甲基噻唑啉-4-羧酸的独特反应。这些结果表明,乙醛和 L-半胱氨酸之间的反应有可能从室内空气中不可逆地去除有毒的乙醛。