直接使用烯丙醇在亚磺酰基咪唑的烯丙基化反应中。

Direct use of allylic alcohols in the allylation of sulfonylimidates.

机构信息

Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO, Japan Science Technology Agency (JST), Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

出版信息

Chem Commun (Camb). 2010 Dec 7;46(45):8662-4. doi: 10.1039/c0cc03067h. Epub 2010 Oct 18.

DOI:10.1039/c0cc03067h

PMID:20953486

Abstract

We have developed catalytic allylation reactions of sulfonylimidates using allylic alcohols as allylating reagents. Stoichiometric amounts of neither activators nor bases are required in this reaction.

摘要

我们开发了使用烯丙醇作为烯丙基化试剂的磺酰亚胺酯的催化烯丙基化反应。在该反应中既不需要活化剂也不需要碱的化学计量。